| |
Jeffrey Allen Phillips
The wetting behavior of fluid
on solid surfaces is of critical importance to many systems- fabrication
of semiconductor devices, application of inks to paper, and even the survival
of animals. One possibility for the fluid is that it completely
wets the surface, forming a thick uniform film. However, if the surface
tensions are altered, the fluid may not wet the surface and instead bead-up
like water on a waxed surface. Wetting phenomena is an issue in all systems
where a fluid phase is at an interface of another fluid and solid (or between
two other fluids). For most systems the substrate is sufficiently
attractive that all fluids wet the interface. However, recently several
new systems have been explored that allow for wetting temperatures where
the fluid goes from a wet to non-wet phase.
Most systems studied display
a first order wetting transition, but it is believed that another variety
of wetting was possible- continuous wetting. For these systems the
film thickness is continuous across the wetting temperature. Continuous,
or second order, wetting has not yet been seen in a physisorbed system.
It was recently predicted that xenon on alkali metals, plated with a monolayer
of gold would be a possible candidate for continuous wetting. With
my experience of first order wetting and preparation of alkali metal surfaces,
I believe that it would be possible to construct an experiment that would
look for this new transition.
The experiment would require a cryostat capable of precise temperature
regulation near the bulk triple point of xenon. The design and construction
of such an apparatus would give a student hands on experience with temperature
control. The elimination of radiant heat, equilibrium time constants,
and handling of cryogenic liquids would be issues that need addressing.
Because surface contamination is of great concern, students would also
be able to work with UHV techniques such as turbo pumps and leak detection.
Surface preparation would likely
be done using evaporative techniques already used in thin film preparation.
Even outside the context of the wetting experiment, the preparation and
analysis of thin films could be a valuable experience for a student.
Measurement of both the substrate and xenon film thickness could be done
with quartz crystal microbalances. These devices allow for resolutions
of fractions of a monolayer, which would be necessary at all stages of
the experiment. Operation of the cryostat will require some computer
programming and interface control for data collection. This experience
with LabVIEW or other similar language would give a student practical experience
for running future experiments.
After completion of the xenon
wetting experiment, the cryostat could be used for any number of low temperature
experiments. One perplexing puzzle in adsorbed films is the solid
layer mobility. For warmer temperatures, when the vapor pressure
is significant, the major process for mass transport is through the vapor.
For situations when the vapor pressure is negligible, there are some questions
as to the mechanism of transport. In my helium experiments it is
seen that at low temperatures, even before the adsorbed film goes superfluid,
the mass transport is very rapid. Experiments have also been performed
on the kinetics of solid hydrogen mobility with little theoretical understanding,
as the transport is not simple diffusion of a 2-D gas. Further work
on these and other systems could be performed with a cryostat that has
optical access. A simple experiment would burn a hole in the adsorbed
film using a heater or laser. Then using ellipsometry techniques
a student would be able to accurately measure the film regrowth as a function
of time. Once optical capabilities have been added to the cryostat,
other experiments on the adsorption and phase transitions of various two-dimensional
films would be possible.
My interests in phase transitions
and soft condensed matter have also grown beyond low temperature physics.
One recent project that I have been working on in my spare time is learning
fluid dynamics. In particular, I want to apply fluid dynamics to
soap film made from standard dishwashing detergent. Several groups
are conducting research on turbulence in soap films suspended between two
nylon wires. This system is incredibly easy to assemble, at least
on the elementary scale, and yet it provides one of the best apparatuses
for testing fluid dynamics in two-dimensions. I’ve been interested
in relating the film thickness, in the laminar regime, to the various fluid
parameters. For a student who enjoys computer modeling this would
be a nice project as they could perform calculations that can be easily
compared with experiments.
Another system that is deceptively
simple to assemble is granular materials. The basic setup for the
study of avalanches, pattern formation and convection only requires a few
trips to the hardware and grocery stores, yet there is much to be learned
from granular materials. While the materials are simple macroscopic
particles, which only interact with repulsive forces, the physics is still
a mystery. A sandpile at rest behaves like a solid, yet if the slope
is increased so that is greater than the angle of repose the grains will
begin to flow. However this movement is not completely fluid-like,
as the Navier-Stokes equations do not hold. The discrete nature of
the particles may imply a gas-like state but the thermal energy of the
system is negligible when compared to the gravitational energy. After
all of the contradictions, one is left to conclude that new laws need to
be found that can predict the behavior of granular materials. The
study of granular materials is a field that rapidly expanding in scope
and popularity as evidenced by the recent articles in Physics Review
Letters, Science, and Nature.
Working on phase transitions
and critical phenomena, especially at low temperatures, is something that
I find very stimulating. However, I think it is possible to use the
experimental techniques I’ve learned to create other experiments.
Experiments such as soap films, granular materials, binary fluids and liquid
crystals can offer students a different type of research experience.
Depending on the student’s interests and personality, working on a smaller,
self-contained project may be more rewarding than working on one portion
of a large experiment. Offering the students different options of
physics and technology could help to match the students with the project
that is best for them.
Return to my Curriculum Vitae |
|